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Dess-Martin periodinane, DMP 1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H) –one 87413-09-0 Melting point 133-134 oC Beilstein
The Dess-Martin periodinane (DMP) is a mild, versatile reagent for selective oxidation of primary andsecondary alcohols to aldehydes and ketones, hydroxamic acids to acyl nitroso compounds,deprotection of thioacetals, deoximation of ketoximes to ketones . Preparations of Dess-Martin Periodinane
Readily Accessible 12-I-5 Oxidant for the Conversion of Primary and Secondary Alcohols toAldehydes and Ketones,Dess, D.B., Martin, J.C., J. Org.Chem. 48 (1983) 4155
A Useful 12-I-5 Triacetoxyperiodinane (the Dess-Martin Periodinane) for Selective Oxidation ofPrimary or Secondary Alcohols and a Variety of Related 12-I-5 Species,Daniel B. Dess and J.C. Martin, J.Am.Chem.Soc., 113 (1991) 7277
An Improved Procedure for the Preparation of the Dess-Martin Periodinane,Robert E. Ireland and Longbin Liu, J.Org.Chem., 58 (1993) 2899
A User-Friendly Entry to 2-Iodoxybenzoic acid (IBX),Marco Frigerio and Marco Santagostino and Simona Sputore, J.Org.Chem., 64 (1999) 4537
Magnesium amide base-mediated enantioselective deprotonation processes,Kenneth W. Henderson, William J. Kerr and Jennifer H. Moir, Tetrahedron, 58 (2002)4573
Applications of of Dess-Martin Periodinane
Readily Accessible 12-I-5 Oxidant for the Conversion of Primary and Secondary Alcohols toAldehydes and Ketones,Dess, D.B., Martin, J.C., J. Org.Chem. 48 (1983) 4155
Enatioselective Total Synthesis of (-)-Preclavulone-A,E.J. Corey and Yi Bin Xiang, Tetrahedron Lett., 29 (1988) 995
Oxidation of Fluoroalkyl-Substituted Carbinols by the Dess-Martin Reagent,Russell J. Linderman and David M. Grave, J.Org.Chem., 54 (1989), 661
Development of a Fully Synthetic Stereoselective Route to 6-Deoxyerythronolide B by ReiterativeApplications of the Lewis Acid Catalyzed Diene Aldehyde Cyclocondensation Reaction: A RemarkableInstance if Diastereofacial Selectivity,David C. Myles and Samuel J. Danishefsky, J.Org.Chem., 55 (1990) 1636
A Useful 12-I-5 Triacetoxyperiodinane (the Dess-Martin Periodinane) for Selective Oxidation ofPrimary or Secondary Alcohols and a Variety of Related 12-I-5 Species,Daniel B. Dess and J.C. Martin, J.Am.Chem.Soc., 113 (1991) 7277
A Novel Application of the Dess-Matrin Reagent to the Synthesis of an FK506 Analogue and otherTricarbonyl Compounds,Mark J. Batchelor, Roger J. Gillespie, Julian M.C. Golec and Charles J. R. Hedgecock, TetrahedronLett., 34 (1993) 167
Hypervalent Iodine Oxidant: Structure and Kinetics of the reactive Intermediates in the Oxidation ofAlcohols an 1,2-Diols by o-Iodoxybenzoic acid (IBX) and Dess-Martin Periodinane. A Comparative H-NMR study. Sergio De Munari, Marco Frigerio and Marco Santagostino, J.Org.Chem., 61 (1996) 9272
The Asymetric Synthesis of Erythromycin B,Stephen F. Martin, Tsuneki Hida, Philip R. Kym, Michael Loft and Anne Hodgson, J.Am.Chem.Soc.,119 (1997) 3193
Deoximation Using Dess-Martin Periodinane: Regeneration of Ketones from Ketoximes,Sachin S. Chaudhari and Krisshnacharya G. Akamanchi, Tetrhedron Lett., 39 (1998) 3209
Reaction of 1,1,1-Trifluoro[chloro]-4-ethoxybut-3-en-2ones with 1,3-Dicarbonyl Compounds: Synthesisof 5-Acetyl[carboxyethyl]-1,1,1-trifluoro[chloro]hept-3-ene-2,6-diones and their Cyclic DerivativesPhenol, Pyridines and Azetone,Nilo Zanatta, Resemario Barichello, Helio G. Bonacorso, Marcos A.P. Martins, Synthesis, 5 (1999) 765
New Synthetic Technology for the Rapid Construction of Novel Heterocycles- Part1:The Reaction of Dess-Martin Periodinane with Anilides and Related Compounds,K.C. Nicolaou, Young-Li Zhong, Phil S. Baran, Angew. Chem.Int.Ed, 39 (2000) 622
New Synthetic Technology for the Rapid Construction of Novel Heterocycles- Part2:The Reaction of Dess-Martin Periodinane with Anilides and Related Compounds,K.C. Nicolaou, Young-Li Zhong, Phil S. Baran, Angew. Chem.Int.Ed, 39 (2000) 625
Oxidation of α,ω-Diols Using the Dess-Martin Periodinane,Jochen Roels, Peter Metz, Synlett, 6 (2001) 789
A Mild, Chemoselective Protocol for the Removal of Thioketals and Thioacetals Mediated by Dess-Martin Periodinane,Neil F. Langille, Less A. Dakin, and James S. Panek, Org.Lett., 5 (2003) 575
Shotgun Process through Differentiation of Aliphatic and Aromatic Aldehyde Functions: The FirstSynthesis of Ferulic Acid Hexan-3-onyl Ether,Yoshifumi Nagano, Akhiro Orita, Junzo Otera, Synlett, 5 (2003) 684
Preparation of 14,36-didehydro pristinamycins IIs,Baptiste Ronan, Eric Bacque, Jean-Claude Barriere and Serge Sable, Tetraherdon, 59 (2003) 2929
Recyclable 2nd generation ionic liquids as green solvents for the oxidation of alcohols with hypervalentiodine reagents,J.S. Yadav, B.V.S. Redy, A.K. Basak and A. Venkat Narsaiah, Tetrahedron, 60 (2004) 2131
Synthesis of Imides, N-Acyl Vinylogous Carbamates and Ureas, and Nitriles by Oxidation of Amidesand Amines with Des-Martin Periodinane,K.C. Nicolaou and Casey J.N. Mathison, Angew.Chem.Int.Ed, 44 (2005) 5992
Syntheses of the cylindrospermopsin alkaloids,Ryan E. Looper, Maria T.C. Runnegar and Robert M. Williams, Tetrahedron, 62 (2006) 4549
Hypervalent Iodine Mediated Intramolecular Cyclization of Thioformanilides: Expeditous Approach to2-Substituted Benzothiazoles,D.Subhas Bose and Mohd. Idrees, J.Org.Chem., 71 (2006) 8261
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BUJNO Synthesis Sp. z o.o.
Preparations of Dess-Martin Periodinane