MATERIAL SAFETY DATA SHEET 1. Chemical Product and Company Identification 1.1. Product Identification: Chemical name: Synonyms:
Phosphoric Acid, mono ammonium salt; Ammonium dihydrogen orthophosphate; Mono ammonium phosphate; Ammonium dihydrogen phosphate; Ammonium phosphate monobasic.
Chemical formula: CAS number: Chemical family: Type of product end use: 1.2. Company Identification: Manufacturer Name & Address:
NovaPeak Division Mishor Rotem, Mobile Post Arava 86800 ISRAEL
Emergency telephone: Non-emergency telephone: 2. Composition / information on ingredients Components Classification
3. Hazards identification
May cause respiratory tract, eye or skin irritation. Harmful if swallowed.
MATERIAL SAFETY DATA SHEET 4. First-aid measures
Rinse out eyes with plenty of water for at least 15
Eye contact
Get medical attention if irritation persists.
Flush skin with plenty of water for at least 15 minutes.
Skin contact
Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if irritation develops.
If inhaled, remove to fresh air immediately.
Inhalation
If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion
Seek immediate medical attention. NOTE: Never give an unconscious person anything to drink.
Extinguishing media
Not combustible. Use extinguishing media appropriate to surrounding fire conditions.
Fire fighting procedure
Call the fire brigade. Avoid breathing the fumes as they may be toxic. Stand upwind of the fire.
In closed stores, provide fire-fighters with self-contained breathing apparatus in positive pressure mode.
Prevent molten or dissolved material to run into drains or watercourse.
Unusual fire and explosion hazards Hazardous decomposition materials Toxic and irritating fumes of ammonia and oxides of (Under Fire Conditions)
nitrogen and of phosphorous may evolve during fires.
As a precaution measure firefighters and others exposed should wear self contained breathing apparatus in
Protective equipment
pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
MATERIAL SAFETY DATA SHEET 6. Accidental release measures Evacuation procedures & Personal
Wear appropriate protective gear for the situation.
precautions
See “Personal Protection” information in Section 8.
Evacuate as needed to perform spill clean-up.
After spillage / leakage
Scoop up, collect and place the product in a clean, labeled container for re-use. Avoid generation of dust.
The remaining product and / or material that can not be salvaged should be cautiously diluted with water and neutralized with an alkaline carbonate or slaked lime, followed by discharge into a treatment system in accordance with all local regulations.
Environmental precaution
Take care to avoid contamination of drains and watercourses, drain system and sewage water.
7. Handling and storage Handling:
When handling the product avoid inhaling of dust and bodily contact. Use appropriate personal protective equipment.
Storage:
Store in a dry, cool, well-ventilated area away from incompatible materials (see "materials to avoid" in section 10). Keep containers tightly closed.
MATERIAL SAFETY DATA SHEET 8. Exposure controls / personal protection Exposure limits:
OSHA and ACGIH have not established specific exposure limits for this material. However, OSHA and ACGIH have established limits for particulates not otherwise regulated (PNOR) and particulates not otherwise classified (PNOC) which are the least stringent exposure limits applicable to dusts.
Inhalable ACGIH TLV Ventilation requirements
Good general ventilation sufficient to maintain TLV-TWA below 3 mg/m³, respirable particles, and 10 mg/m³, inhalable particles.
Personal protection equipment: Respiratory protection
Wear NIOSH approved respiratory protective equipment when exposure exceeds the OSHA nuisance dust standard of 15 mg/m3 or the ACGIH nuisance dust limit of 10 mg/m3 for the eight hour time weighted average. When stored in closed area, a self-contained breathing apparatus is required to protect against ammonia gas.
Skin protection
Wear appropriate protective gloves in compliance with the European Directive 89/686/EEC and standard EN374.
Eye /Face protection
Eye and face protection requirements will vary dependent upon work environment conditions and material handling practices. Appropriate ANSI Z87 approved equipment should be selected for the particular use intended for this material.
Use chemical safety glasses with side shields or splash proof goggles. Face contact should be prevented through use of a face shield.
Industrial hygiene
Avoid contact with skin and eyes and inhalation of hot vapours.
Do not eat, drink or smoke until after-work showering and changing clothes.
MATERIAL SAFETY DATA SHEET 9. Physical and chemical properties Appearance Melting point/range Thermal decomposition Boiling point/range Vapour pressure Specific gravity, at 25˚C (77˚ F) Relative vapour density (air=1) Flash point Flammable/Explosion limits Auto-ignition temperature Water Solubility, at 25˚C (77˚ F) pH (1% solution in water) 10. Stability and reactivity Chemical stability Incompatibility with other materials
Strong bases and acids, sodium hypochlorite, copper and its alloys.
Hazardous Decomposition Products
Oxides of phosphorus, Nitrogen oxides (NOx) and Ammonia. Ammonia is also released under basic conditions. These are irritating and toxic fumes and gases.
Hazardous polymerization MATERIAL SAFETY DATA SHEET 11. Toxicological information Acute oral toxicity to Rat, LD50 Acute dermal toxicity to Rabbit, Skin Irritation, Rabbit Eye Irritation, Rabbit Skin Sensitization, guinea pigs Ames Test, Salmonella typhimurium & Escherichia coli Long-term toxicity: Carcinogenicity: NTP 11th Report on Carcinogens 12. Ecological information Environmental Fate:
When released into soil, this material may leach into groundwater.
- Ammonium ions, that are toxic to fish, are liberated.
- Phosphate ions liberated contribute to eutrophication
Persistence / Degradability:
Phosphates are converted to calcium or iron / aluminium phosphates, and are incorporated into the organic soil matter/
Bio accumulation: Ecotoxicity MATERIAL SAFETY DATA SHEET 13. Disposal considerations Waste disposal
Dispose to an authorized waste facility following the instruction in section 6 of this MSDS.
Prevent discharging of waste into watercourses and drains.
Observe all local environmental regulations when disposing of this material.
Contaminated packaging
Disposal of empty packaging should be in accordance with local environmental regulations. 14. Transportation information ICAO/IATA Canada TDG 15. Regulatory information
This chemical substance is not classified in the Annex I of Directive 67/548/EEC
Inventory Status Inventory MATERIAL SAFETY DATA SHEET 16. Other information
Text of R Phrases mentioned in Section 2
Introduction of a Specific European Version
Key Legend Information:
ACGIH - American Conference of Governmental Industrial Hygienists
OSHA - Occupational Safety and Health Administration
IARC - International Agency for Research on Cancer
Although the information and recommendations set forth herein (hereinafter "information") are presented in good faith and believed to be correct as of the date hereof, Rotem Amfert Negev Ltd. makes no representations as to the completeness or accuracy thereof. Information is supplied upon the condition that the persons receiving same will make their own determination as to its safety and suitability for their purposes prior to use. In no event will Rotem Amfert Negev Ltd. be responsible for damages of any nature whatsoever resulting from the use of or reliance upon information. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE, ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH THE INFORMATION REFERS. MSDS prepared by HSE Specialist according to Commission Directives 1999/45/EC and 2001/58/EC. Tel.: +972-8-6465 341 Fax.: +972-8-6465 342 E-mail:lati@dsw.co.il End of safety data sheet
Rare earth elements as alternative growth promoters in pig production Institute for Animal Physiology, Physiological Chemistry and Animal Nutrition,Ludwig-Maximilians-University Munich, GermanyInstitute for Animal Physiology, Physiological Chemistry and Animal Nutrition,alternative growth promoter _ feed conversion ratio _ in-feed antibiotics _ lanthanidesGrowth promoters or performance enh