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Microsoft word - permerid 500 ec.doc

Product Name: Permerid 500 EC Insecticide
Page: 1 of 5
This revision issued: February, 2010
SECTION 1 - IDENTIFICATION OF CHEMICAL PRODUCT AND COMPANY
United Phosphorus Ltd,
Norwest Business Park, Bella Vista, NSW 2153 Substance:
Trade Name:
Permerid 500 EC Insecticide
Product Use:
Insecticide used in agricultural applications and timber treatment. Creation Date:
September, 2007
This version issued:
February, 2010
Section 2 - Hazards Identification
Statement of Hazardous Nature
This product is classified as: Xn, Harmful. Xi, Irritating. N, Dangerous to the environment. Hazardous according to the criteria of SWA. Not subject to the ADG Code when transported by Road or Rail. (ADG 7, Special Provision AU01). Risk Phrases: R22, R43, R51. Harmful if swallowed. May cause sensitisation by skin contact. Toxic to aquatic
organisms.
Safety Phrases: S20, S23, S25, S28, S36. When using, do not eat or drink. Do not breathe spray mists. Avoid
contact with eyes. After contact with skin, wash immediately with plenty of soap and water. Wear suitable protective
clothing.
SUSDP Classification: S6
ADG Classification: Class 9: Miscellaneous dangerous goods.
UN Number: 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Emergency Overview
Physical Description & colour
: Clear, colourless liquid.
Odour: Characteristic liquid hydrocarbon odour.
Major Health Hazards: Permethrin is harmful to non-harmful via the oral route, with a reported LD50 for technical
Permethrin in rats of 430 to 4000 mg/kg. Via the dermal route, it is not harmful, with a reported dermal LD50 in rats of
over 4000 mg/kg, and in rabbits of greater 2000 mg/kg. harmful if swallowed, possible skin sensitiser.
Potential Health Effects
See section 11 for Chronic exposure studies.
Inhalation:
Short term exposure:
Available data indicates that this product is not harmful. However product may be mildly
irritating, although unlikely to cause anything more than mild transient discomfort.
Skin Contact:
Short term exposure:
Classified as a potential sensitiser by skin contact. Exposure to a skin sensitiser, once
sensitisation has occurred, may manifest itself as skin rash or inflammation, and in some individuals this reaction can
be severe. In addition product may be irritating, but is unlikely to cause anything more than mild transient discomfort.
Eye Contact:
Short term exposure:
This product is believed to be mildly irritating, to eyes, but is unlikely to cause anything more
than mild transient discomfort.
Ingestion:
Short term exposure:
Significant oral exposure is considered to be unlikely. Available data shows that this product
is harmful, but symptoms are not available. However, this product may be irritating to mucous membranes but is
unlikely to cause anything more than transient discomfort.
Carcinogen Status:
SWA: No significant ingredient is classified as carcinogenic by SWA.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: Permethrin is Class 3 - unclassifiable as to carcinogenicity to humans.
See the IARC website for further details. A web address has not been provided as addresses frequently change.
MATERIAL SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Permerid 500 EC Insecticide
Page: 2 of 5
This revision issued: February, 2010
Section 3 - Composition/Information on Ingredients
Ingredients
TWA (mg/m3) STEL
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non hazardous ingredients are also possible. The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly. Section 4 - First Aid Measures
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this MSDS with you when you call. Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
Skin Contact: Wash gently and thoroughly with water (use non-abrasive soap if necessary) for 5 minutes or until
chemical is removed.
Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes or until
the product is removed, while holding the eyelid(s) open. Obtain medical advice immediately if irritation occurs. Take
special care if exposed person is wearing contact lenses.
Ingestion: If swallowed, do NOT induce vomiting. Wash mouth with water and contact a Poisons Information
Centre, or call a doctor.
Section 5 - Fire Fighting Measures
Fire and Explosion Hazards
: This product is classified as a C1 combustible product. There is a slight risk of an
explosion from this product if commercial quantities are involved in a fire. Violent steam generation or eruption may
occur upon application of direct water stream on hot liquids. Vapours from this product are heavier than air and may
accumulate in sumps, pits and other low-lying spaces, forming potentially explosive mixtures. They may also flash
back considerable distances.
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.
Extinguishing Media: Alcohol resistant foam is the preferred firefighting medium but, if it is not available, normal
foam can be used. Try to contain spills, minimise spillage entering drains or water courses.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade. There is little danger of
a violent reaction or explosion if significant quantities of this product are involved in a fire. Recommended personal
protective equipment is full fire kit and and breathing apparatus.
Flash point:
<70°C
Upper Flammability Limit: No
Lower Flammability Limit: No
Autoignition temperature: Approx
Flammability Class: C1
Section 6 - Accidental Release Measures
Accidental release:
In the event of a major spill, prevent spillage from entering drains or water courses. Wear full
protective clothing including eye/face protection. All skin areas should be covered. See below under Personal
Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective
clothing include rubber, PVC. Eye/face protective equipment should comprise as a minimum, protective goggles. If
there is a significant chance that vapours or mists are likely to build up in the cleanup area, we recommend that you
use a respirator. Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned below (section 8).
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill
is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains
or waterways. Because of the environmentally hazardous nature of this product, special care should be taken to
restrict release to waterways or drains. Sweep up and shovel or collect recoverable product into labelled containers
for recycling or salvage, and dispose of promptly. Recycle containers wherever possible after careful cleaning. Refer
to product label for specific instructions. After spills, wash area preventing runoff from entering drains. If a significant
MATERIAL SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Permerid 500 EC Insecticide
Page: 3 of 5
This revision issued: February, 2010
quantity of material enters drains, advise emergency services. Full details regarding disposal of used containers, spillage and unused material may be found on the label. If there is any conflict between this MSDS and the label, instructions on the label prevail. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry. Section 7 - Handling and Storage
Handling:
Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage:
This product is a Scheduled Poison. Observe all relevant regulations regarding sale, transport and storage
of this schedule of poison. Check packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection
The following Australian Standards will provide general advice regarding safety clothing and equipment: Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial Eye
Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
SWA Exposure Limits
TWA (mg/m3) STEL
Exposure limits have not been established by SWA for any of the significant ingredients in this product. The ADI for permethrin is set at 0.05mg/kg/day. The corresponding NOEL is set at 5mg/kg/day. ADI means Acceptable Daily Intake and NOEL means No-observable-effect-level. Values taken from Australian ADI List, Dec 2006. No special equipment is usually needed when occasionally handling small quantities. The following instructions are
for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that
the work environment remains clean and that vapours and mists are minimised.
Eye Protection: Eye protection such as protective glasses or goggles is recommended when product is being used.
Skin Protection: If you believe you may have a sensitisation to this product or any of its declared ingredients, you
should prevent skin contact by wearing impervious gloves, clothes and, preferably, apron. Make sure that all skin
areas are covered. See below for suitable material types.
Protective Material Types: We suggest that protective clothing be made from the following: rubber, PVC.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned above.
Safety deluge showers should, if practical, be provided near to where this product is being used.
Section 9 - Physical and Chemical Properties:
Physical Description & colour
: Clear, colourless liquid.
Odour:
Characteristic liquid hydrocarbon odour. Boiling Point:
Freezing/Melting Point:
No specific data. Liquid at normal temperatures. Volatiles:
No specific data. Expected to be low at 100°C but up to 50% at higher temperatures. Vapour Pressure: No
Vapour Density: No
Specific Gravity:
Water Solubility: Emulsifiable.
pH: No
Volatility: No
Evaporation Rate: No
Coeff Oil/water distribution: No
Autoignition temp: Approx
Section 10 - Stability and Reactivity
Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have
any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: Store in the closed original container in a dry, cool, well-ventilated area out of direct sunlight.
MATERIAL SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Permerid 500 EC Insecticide
Page: 4 of 5
This revision issued: February, 2010
Incompatibilities: strong acids, strong bases, strong oxidising agents.
Fire Decomposition: Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Water.
Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision,
disturbance of judgment, and unconsciousness followed by coma and death.
Polymerisation:
Polymerisation reactions are unlikely; they are not expected to occur.
Section 11 - Toxicological Information
Toxicity: Acute toxicity:
Permethrin is harmful to non-harmful via the oral route, with a reported LD50 for technical
Permethrin in rats of 430 to 4000 mg/kg. Via the dermal route, it is not harmful, with a reported dermal LD50 in rats of
over 4000 mg/kg, and in rabbits of greater 2000 mg/kg. Permethrin caused mild irritation of both the intact and
abraded skin of rabbits. It also caused conjunctivitis when it was applied to the eyes. The 4-hour inhalation LC50 for
rats was greater than 23.5 mg/L, indicating practically no inhalation toxicity. The toxicity of Permethrin is dependent
on the ratio of the isomers present; the cis-isomer being more toxic.
Chronic toxicity: No adverse effects were observed in dogs fed Permethrin at doses of 5 mg/kg/day for 90 days.
Rats fed 150 mg/kg/day for 6 months showed a slight increase in liver weights. Very low levels of Permethrin in the
diet of chickens (0.1 ppm for 3 to 6 weeks after hatching) have been reported to suppress immune system activity.
Reproductive effects: The fertility of female rats was affected when they received very high oral doses of 250
mg/kg/day of Permethrin during the 6th to 15th day of pregnancy. It is not likely that reproductive effects will be seen
in humans under normal circumstances.
Teratogenic effects: Permethrin is reported to show no teratogenic activity.
Mutagenic effects: Permethrin is reported to show no mutagenic activity.
Carcinogenic effects: The evidence regarding the carcinogenicity of Permethrin is inconclusive.
Organ toxicity: Permethrin is suspected of causing liver enlargement of the liver and nerve damage. Effects on the
immune system have been noted in animal studies.
Fate in humans and animals: Permethrin is efficiently metabolized by mammalian livers. Breakdown products, or
"metabolites," of Permethrin are quickly excreted and do not persist significantly in body tissues. When Permethrin is
administered orally to rats, it is rapidly metabolized and almost completely eliminated from the body in a few days.
Only 3 to 6% of the original dose was excreted unchanged in the faeces of experimental animals. Permethrin may
persist in fatty tissues, with half-lives of 4 to 5 days in brain and body fat. Permethrin does not block, or inhibit,
cholinesterase enzymes.
Section 12 - Ecological Information
Toxic to aquatic organisms. This product is biodegradable. It will not accumulate in the soil or water or cause long
term problems.
Effects on birds: Permethrin is practically non-toxic to birds. The oral LD50 for a Permethrin formulation is greater
than 9900 mg/kg in mallard ducks, greater than 13,500 mg/kg in pheasants, and greater than 15,500 mg/kg in
Japanese quail.
Effects on aquatic organisms: Aquatic ecosystems are particularly vulnerable to the impact of Permethrin. A fragile
balance exists between the quality and quantity of insects and other invertebrates that serve as fish food. The 48-hour
LC50 for rainbow trout is 0.0125 mg/L for 24 hours, and 0.0054 mg/L for 48 hours. The 48-hour LC50 in bluegill sunfish
and salmon is 0.0018 mg/L. As a group, synthetic pyrethroids were toxic to all estuarine species tested. They had a
96-hour LC50 of less than or equal to 0.0078 mg/L for these species. The bioconcentration factor for Permethrin in
bluefish is 715 times the concentrations in water and is 703 in catfish. This indicates that the compound has a low to
moderate potential to accumulate in these organisms.
Effects on other organisms: Permethrin is extremely toxic to bees. Severe losses may be expected if bees are
present at treatment time, or within a day thereafter. Permethrin is also toxic to wildlife. It should not be applied, or
allowed to drift, to crops or weeds in which active foraging takes place.
Environmental Fate:
Breakdown in soil and groundwater:
Permethrin is of low to moderate persistence in the soil environment, with
reported half-lives of 30 to 38 days. Permethrin is readily broken down, or degraded, in most soils except organic
types. Soil microorganisms play a large role in the degradation of Permethrin in the soil. The addition of nutrients to
soil may increase the degradation of Permethrin. It has been observed that the availability of sodium and
phosphorous decreases when Permethrin is added to the soil. Permethrin is tightly bound by soils, especially by
organic matter. Very little leaching of Permethrin has been reported. It is not very mobile in a wide range of soil types.
Because Permethrin binds very strongly to soil particles and is nearly insoluble in water, it is not expected to leach or
to contaminate groundwater.
Breakdown in water: The results of one study near estuarine areas showed that Permethrin had a half-life of less
than 2.5 days. When exposed to sunlight, the half-life was 4.6 days. Permethrin degrades rapidly in water, although it
can persist in sediments. There was a gradual loss of toxicity after Permethrin aged for 48 hours in sunlight at 0.05
mg/L in water.
Breakdown in vegetation: Permethrin is not phytotoxic, or poisonous, to most plants when it is used as directed.
Some injury has occurred on certain ornamental plants. No incompatibility has been observed with Permethrin on
MATERIAL SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Permerid 500 EC Insecticide
Page: 5 of 5
This revision issued: February, 2010
cultivated plants. Treated apples, grapes, and cereal grains contain <1mg/kg of Permethrin at harvest time. Section 13 - Disposal Considerations
Disposal:
There are many pieces of legislation covering waste disposal and they differ in each state and territory, so
each user must refer to laws operating in their area. In some areas, certain wastes must be tracked. The Hierarchy of
Controls seems to be common - the user should investigate: Reduce, Reuse, and Recycle and only if all else fails
should disposal be considered. Note that properties of a product may change in use, so that the following suggestions
may not always be appropriate. The following may help you in properly addressing this matter for this product. Special
help is available for the disposal of Agricultural Chemicals. The product label will give general advice regarding
disposal of small quantities, and how to cleanse containers. However, for help with the collection of unwanted rural
chemicals, contact ChemClear 1800 008 182 http://www.chemclear.com.au/ and for help with the disposal of empty
drums, contact DrumMuster http://www.drummuster.com.au/ where you will find contact details for your area.
Section 14 - Transport Information
Not subject to the ADG Code when transported by Road or Rail in containers up to 500L or kg.
(ADG 7, Special Provision AU01).

ADG Code: 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Hazchem Code: 3Z
Special Provisions: 179, 274, AU01
Limited quantities: ADG 7 specifies a Limited Quantity value of 5 L for this class of product.
Dangerous Goods Class: Class 9, Miscellaneous Dangerous Goods.
Packaging Group: III
Packaging Method: P001, IBC03, LP01
Class 9 Miscellaneous Dangerous Goods shall not be loaded in the same vehicle or packed in the same freight container with Dangerous Goods of Class 1 (Explosives). Section 15 - Regulatory Information
AICS:
All of the significant ingredients in this formulation are compliant with NICNAS regulations.
The following ingredients: Petroleum spirit, permethrin are mentioned in the SUSDP.
Section 16 - Other Information
This MSDS contains only safety-related information. For other data see product literature.
Acronyms:
ADG Code

Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition Australian Inventory of Chemical Substances Safe Work Australia, formerly ASCC and NOHSC CAS number
Chemical Abstracts Service Registry Number Hazchem Code
Emergency action code of numbers and letters that provide information to emergency services especially firefighters International Agency for Research on Cancer R-Phrase Risk
Standard for the Uniform Scheduling of Drugs & Poisons UN Number United
THIS MSDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS MSDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE. IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST. Please read all labels carefully before using product. This MSDS is prepared in accord with the SWA document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)] Copyright Kilford & Kilford Pty Ltd, February, 2010. http://www.kilford.com.au/ Phone (02)9251 4532 MATERIAL SAFETY DATA SHEET
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

Source: http://my.uplonline.com/uplaustralia/productdata/Permerid500.pdf

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