Pest-control-north.co.uk

SAFETY DATA SHEET
Permethrin 25% WP
Revision
Revision date
1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND THE COMPANY
Product name
Permethrin 25% WP
Hockley International Ltd
Hockley House
354 Park Lane
Poynton
Stockport
SK12 1RL
Telephone
01625 878590
01625 877285
2. COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous ingredients
Symbols/Risk phrases
Permethrin (ISO)
52645-53-1
258-067-9
Xn; R20/22 R43 N; R50/53
Suspending Agent 200
7631-86-9
Xi; R36/37/38
Calcium Silicate
1344-95-2
(Calcium silicate respirable)
Kaolin China Clay
1332-58-7
(Kaolin, respirable dust)
3. HAZARDS IDENTIFICATION
Main hazards
Harmful by inhalation and if swallowed. May cause sensitisation by skin contact. Very
toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
4. FIRST AID MEASURES
Skin contact
Wash off immediately with plenty of soap and water. Remove contaminated clothing.
May cause irritation to skin. Seek medical attention if irritation or symptoms persist.
Eye contact
Rinse immediately with plenty of water for 15 minutes holding the eyelids open. Contact
lenses should be removed. May cause irritation to eyes. Seek medical attention.
Inhalation
Move the exposed person to fresh air. If breathing stops, provide artificial respiration.
Seek medical attention.
Ingestion
Immediate medical attention is required. DO NOT INDUCE VOMITING. Drink 1 to 2
glasses of water. Never give anything by mouth to an unconscious person.
General information
In case of accident or if you feel unwell, seek medical advice immediately (show the
label where possible).
Print date
5-Nov-2007
Permethrin 25% WP
Revision
Revision date
5. FIRE FIGHTING MEASURES
Extinguishing media
Carbon dioxide (CO2) Dry chemical. Foam. Water spray.
Do NOT use . Water jet.
Fire hazards
Do not release chemically contaminated water into drains, soil or surface water. Take
care to retain water used for extinguishing and dispose of according to local regulations.
Burning produces compounds of carbon, oxygen and chlorine.
Protective equipment
Wear: Self-contained breathing apparatus.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Ensure adequate ventilation of the working area. Wear suitable protective equipment.
Environmental precautions
Do not let product contaminate subsoil. Do not allow product to enter drains. Do not
flush into surface water. Prevent further spillage if safe.
Clean up methods
Avoid raising dust. Sweep up. Transfer to a closable, labelled salvage container for
disposal by an appropriate method.
7. HANDLING AND STORAGE
Handling
Avoid contact with eyes and skin. Do not breathe gas/fumes/vapour/spray. Do not
empty into drains. Ensure adequate ventilation of the working area. Wear suitable
protective equipment. Do not eat, drink or smoke in areas where this product is used or
stored.
Keep in a cool, dry, well ventilated area. Keep containers tightly closed. Store at
temperatures below 30 °C. Keep away from food, drink and animal feedingstuffs. Keep
out of the reach of children.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure limits
Calcium Silicate
WEL 8-hr limit ppm: -
WEL 8-hr limit mg/m3: 4
(Calcium silicate respirable)
WEL 15 min limit ppm: -
WEL 15 min limit mg/m3: -
Calcium Silicate
WEL 8-hr limit ppm: -
WEL 8-hr limit mg/m3: 10
(Calcium silicate total inhalable dust)
WEL 15 min limit ppm: -
WEL 15 min limit mg/m3: -
Kaolin China Clay
WEL 8-hr limit ppm: -
WEL 8-hr limit mg/m3: 2
(Kaolin, respirable dust)
WEL 15 min limit ppm: -
WEL 15 min limit mg/m3: -
Engineering measures
Ensure adequate ventilation of the working area.
Respiratory protection
Suitable half mask respirator with filter P3 (EN 143)
Hand protection
Chemical resistant gloves (PVC)
Eye protection
Face shield. Approved safety goggles.
Protective equipment
Chemical resistant clothing. Rubber boots.
Print date
5-Nov-2007
Permethrin 25% WP
Revision
Revision date
9. PHYSICAL AND CHEMICAL PROPERTIES
Description
Characteristic.
Flash point
Flammability limits
Not Flammable
Explosive
Oxidising
Relative density
0.60 +/- 0.05 @ 20°C
Autoignition temperature
> 450°C
10. STABILITY AND REACTIVITY
Stability
Stable under normal conditions. Decomposition will start at 100°C.
Conditions to avoid
Direct sunlight.
Materials to avoid
Strong oxidising agents.
Hazardous decomposition
Burning produces compounds of carbon, oxygen and chlorine.
products
11. TOXICOLOGICAL INFORMATION
Toxicological information
Permethrin 25% WP
Oral Mouse LD50 = 2,160 mg/kg
Dermal Rat LD50 = > 10,000 mg/kg
Oral Rat LD50 = 1,750 mg/kg
Dermal Rabbit LD50 = > 8,000 mg/kg
Inhalation Rat LC50/ 4 h = > 25.0 mg/l
Permethrin (ISO)
Oral Mouse LD50 = 2,160 mg/kg
Dermal Rat LD50 = > 10,000 mg/kg
Oral Rat LD50 = 1,750 mg/kg
Dermal Rabbit LD50 = > 8,000 mg/kg
Inhalation Rat LC50/ 4 h = > 25.0 mg/l
Suspending Agent 200
Oral Mouse LD50 = 2,160 mg/kg
Dermal Rat LD50 = > 10,000 mg/kg
Oral Rat LD50 = 1,750 mg/kg
Dermal Rabbit LD50 = > 8,000 mg/kg
Inhalation Rat LC50/ 4 h = > 25.0 mg/l
Corrosivity
May cause irritation to eyes. May cause irritation to skin.
Sensitization
May cause sensitisation by skin contact.
Repeated or prolonged
Prolonged or repeated exposure may cause irritation to skin and mucous membranes.
exposure
May cause allergic reactions in susceptible people.
Mutagenic effects
Carcinogenic effects
Reproductive toxicity
Print date
5-Nov-2007
Permethrin 25% WP
Revision
Revision date
12. ECOLOGICAL INFORMATION
Ecotoxicity
Permethrin 25% WP
Daphnia LC50/48h = 2.40 ug/l
Rainbow trout LC50/96h = 10.0 ug/l
Bluegill sunfish LC50/96h = 7.20 ug/l
Quail LC50/8 days = > 10,000 mg/kg
Permethrin (ISO)
Daphnia LC50/48h = 2.40 ug/l
Rainbow trout LC50/96h = 10.0 ug/l
Bluegill sunfish LC50/96h = 7.20 ug/l
Quail LC50/8 days = > 10,000 mg/kg
Suspending Agent 200
Daphnia LC50/48h = 2.40 ug/l
Rainbow trout LC50/96h = 10.0 ug/l
Bluegill sunfish LC50/96h = 7.20 ug/l
Quail LC50/8 days = > 10,000 mg/kg
Mobility
Mobile in most soils.
Degradability
Water endangering.
13. DISPOSAL CONSIDERATIONS
General information
Do not empty into drains. NB: The user's attention is drawn to the possible existence of
regional or national regulations regarding disposal.
Disposal methods
Can be incinerated if in compliance with local and national regulations. Can be sent to
landfill if in compliance with local and national regulations.
Disposal of packaging
Empty containers can be sent to landfill after cleaning, if in compliance with local and
national regulations.
14. TRANSPORT INFORMATION
Packing group III
Hazard ID 90
Proper Shipping ENVIRONMENTALLY
Name HAZARDOUS SUBSTANCE,
SOLID, N.O.S, (contains
Permethrin).
Packing group III
Marine pollutant YES
EmS Code F-A S-F
Packing group III
Subsidiary risk -
Packing Instruction 911
Maximum quantity 400 kg
Packing Instruction 911
Maximum quantity 400 kg
(Passenger)
Print date
5-Nov-2007
Permethrin 25% WP
Revision
Revision date
15. REGULATORY INFORMATION
Xn - Harmful; N - Dangerous for the environment
Risk phrases
R36/38 - Irritating to eyes and skin.
R20/22 - Harmful by inhalation and if swallowed.
R43 - May cause sensitisation by skin contact.
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Safety phrases
S23 - Do not breathe gas/fumes/vapour/spray.
S24 - Avoid contact with skin.
S29 - Do not empty into drains.
S37 - Wear suitable gloves.
S42 - During fumigation/spraying wear suitable respiratory equipment.
S51 - Use only in well-ventilated areas.
16. OTHER INFORMATION
Text of risk phrases in
R20/22 - Harmful by inhalation and if swallowed.
Section 2
R36/37/38 - Irritating to eyes, respiratory system and skin.
R43 - May cause sensitisation by skin contact.
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Print date
5-Nov-2007

Source: http://www.pest-control-north.co.uk/documents/data-sheets/rodenticides/Permethrin-WP.pdf