Aquaspersions.co.uk

SAFETY DATA SHEET
Compilation date: 18/05/12
Revision No: 4
Section 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name: 50% THIRAM
Product code: fTHIR/50
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of substance / mixture: Contains: Tetramethylthiuram disulphide. For use in pesticide formulations.
1.3. Details of the supplier of the safety data sheet
Company name: Aquaspersions Ltd
Tel: 01422 386200
Fax: 01422 386239
Email: technical@aquaspersions.co.uk
1.4. Emergency telephone number
Emergency tel: 01422 386200
Section 2: Hazards identification
2.1. Classification of the substance or mixture
Classification under CHIP: Xn: R20/22; Xi: R36/38; Sens.: R43; Xn: R48/22; N: R50/53
Classification under CLP: Acute Tox. 4: H302; Eye Irrit. 2: H319; Aquatic Acute 1: H400; Aquatic Chronic 1: H410;
Skin Irrit. 2: H315; Skin Sens. 1: H317; STOT RE 2: H373 Most important adverse effects: Harmful by inhalation and if swallowed. Irritating to eyes and skin. May cause
sensitisation by skin contact. Harmful: danger of serious damage to health by prolonged exposure if swallowed. Very toxic to aquatic organisms, may cause long-term adverse 2.2. Label elements
Label elements under CLP:
Hazard statements: H302: Harmful if swallowed.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H373: May cause damage to organs through prolonged or repeated exposure.
H410: Very toxic to aquatic life with long lasting effects.
SAFETY DATA SHEET
Signal words: Warning
Hazard pictograms: GHS07: Exclamation mark
Precautionary statements: P260: Do not breathe dust/fumes/gas/mist/vapours/spray.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get medical advice if you feel unwell.
P321: Specific treatment (see instructions on this label).
Label elements under CHIP:
Hazard symbols: Harmful.
Risk phrases: R20/22: Harmful by inhalation and if swallowed.
R36/38: Irritating to eyes and skin.
R43: May cause sensitisation by skin contact.
R48/22: Harmful: danger of serious damage to health by prolonged exposure if R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the Safety phrases: S24: Avoid contact with skin.
S61: Avoid release to the environment. Refer to special instructions / safety data sheets.
2.3. Other hazards
PBT: This substance is not identified as a PBT substance.
Section 3: Composition/information on ingredients
3.2. Mixtures
Hazardous ingredients:
SAFETY DATA SHEET
Section 4: First aid measures
4.1. Description of first aid measures
Skin contact: If a person feels unwell after coming into contact with this dispersion then seek medical
advice. Remove contaminated clothing. Wash thoroughly with soap and water. Eye contact: Irrigate with plenty of water. Seek medical advice
Ingestion: Do not induce vomiting. Wash out mouth with water and give 200-300ml warm water to
drink. Seek medical attention immediately. Alcohol intolerance (Antabuse syndrome) Inhalation: Remove patient to fresh air. Treat symptomatically and seek medical advice. In the
unlikely event that this substance is inhaled (e.g. aspiration) then treat symptomatically 4.2. Most important symptoms and effects, both acute and delayed
Skin contact: There may be irritation and redness at the site of contact.
Eye contact: There may be pain and redness.
Ingestion: Nausea and stomach pain may occur.
Inhalation: There may be irritation of the throat with a feeling of tightness in the chest.
4.3. Indication of any immediate medical attention and special treatment needed
Section 5: Fire-fighting measures
5.1. Extinguishing media
Extinguishing media: Water. Carbon dioxide. Alcohol or polymer foam. Dry chemical powder. Do not use water
5.2. Special hazards arising from the substance or mixture
Exposure hazards: Thermal decomposition or burning may release oxides of carbon, phosphorous and
other toxic gases or vapours. Do not release chemically contaminated water into drains, soil or surface water. Sufficient measures must be taken to retain water used for exting 5.3. Advice for fire-fighters
Advice for fire-fighters: Respiratory Protective Equipment (RPE) must be worn.
Section 6: Accidental release measures
SAFETY DATA SHEET
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions: Avoid contact with skin/eyes. Do not inhale mists. Avoid ingestion.
6.2. Environmental precautions
Environmental precautions: Prevent contamination of drains/watercourses/vegetation. Advise police.
6.3. Methods and material for containment and cleaning up
Clean-up procedures: Adsorb onto sand/earth/similar adsorbent material. Once clear, wash the spillage area
clean with water and detergent. Shovel up into drums or suitable containers for 6.4. Reference to other sections
Section 7: Handling and storage
7.1. Precautions for safe handling
Handling requirements: Ensure there is sufficient ventilation of the area. Avoid contact with skin/eyes. Do not
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions: Store in closed containers, well protected from frost. Stir well before use.
Suitable packaging: Most packagaing suitable, avoid mild-steel.
7.3. Specific end use(s)
Section 8: Exposure controls/personal protection
8.1. Control parameters
Hazardous ingredients:
TETRAMETHYLTHIURAM DISULPHIDE
Workplace exposure limits:
Respirable dust
8.2. Exposure controls
Engineering measures: Ensure there is sufficient ventilation of the area.
Respiratory protection: Wear suitable respiratory protective equipment to prevent overexposure to mist.
Hand protection: Protective gloves. Water repellant barrier cream
Eye protection: Safety goggles. Face-shield. Ensure eye bath is to hand.
Skin protection: Wear suitable protective clothing. Water-repellent barrier cream.
Section 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
State: Liquid
SAFETY DATA SHEET
Colour: Off-white
Odour: Barely perceptible odour
Evaporation rate: Negligible
Solubility in water: Miscible
Viscosity: Non-viscous
Boiling point/range°C: 100
Melting point/range°C: 0
Relative density: 1.18-1.2
pH: 8.0 - 10.0
9.2. Other information
Other information: Not applicable.
Section 10: Stability and reactivity
10.1. Reactivity
Reactivity: Stable under recommended transport or storage conditions.
10.2. Chemical stability
Chemical stability: Stable under normal conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.
10.4. Conditions to avoid
Conditions to avoid: Heat.
10.5. Incompatible materials
Materials to avoid: Strong acids. Strong bases. Oxidising agents.
10.6. Hazardous decomposition products
Section 11: Toxicological information
11.1. Information on toxicological effects
Relevant effects for mixture:
Symptoms / routes of exposure
Skin contact: There may be irritation and redness at the site of contact.
Eye contact: There may be pain and redness.
Ingestion: Nausea and stomach pain may occur.
Inhalation: There may be irritation of the throat with a feeling of tightness in the chest.
SAFETY DATA SHEET
Section 12: Ecological information
12.1. Toxicity
Ecotoxicity values: Not applicable.
12.2. Persistence and degradability
Persistence and degradability: No data available.
12.3. Bioaccumulative potential
Bioaccumulative potential: No data available.
12.4. Mobility in soil
Mobility: Miscible with water.
12.5. Results of PBT and vPvB assessment
PBT identification: This substance is not identified as a PBT substance.
12.6. Other adverse effects
Other adverse effects: No data avilaible.
Section 13: Disposal considerations
13.1. Waste treatment methods
Disposal of packaging: Dispose of in a regulated landfill site or other method for hazardous or toxic wastes.
NB: The user's attention is drawn to the possible existence of regional or national
Section 14: Transport information
14.1. UN number
UN number: UN3082
14.2. UN proper shipping name
Shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
14.3. Transport hazard class(es)
Transport class: 9
14.4. Packing group
Packing group: III
14.5. Environmental hazards
Environmentally hazardous: Yes
Marine pollutant: No
14.6. Special precautions for user
SAFETY DATA SHEET
Section 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.2. Chemical Safety Assessment
Chemical safety assessment: A chemical safety assessment has not been carried out for the substance or the mixture
Section 16: Other information
Other information
Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No
Phrases used in s.2 and 3: EUH401: To avoid risks to human health and the environment, comply with the
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H373: May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H410: Very toxic to aquatic life with long lasting effects.
R20/22: Harmful by inhalation and if swallowed.
R36/38: Irritating to eyes and skin.
R43: May cause sensitisation by skin contact.
R48/22: Harmful: danger of serious damage to health by prolonged exposure if R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive
and shall be used only as a guide. Aquaspersions Limited shall not be held liable for any damage resulting from handling or from contact with the above product.

Source: http://aquaspersions.co.uk/wp-content/uploads/2012/05/50-Thiram.v4clp.pdf